Parallels Desktop 5 for Mac and Parallels Desktop 6 for Mac will not run on Mac OS X Mountain Lion.
Parallels Desktop 5 for Mac and Parallels Desktop 6 for Mac customers, who wish to take advantage of the new Mac OS X Mountain Lion features, should install Parallels Desktop 9 for Mac, which can be downloaded here.
IMPORTANT: Parallels Desktop 5 and Parallels Desktop 6 users will need to purchase a full copy of Parallels Desktop 9 for Mac, as version 5 and version 6 fall under the End-of-Life policy and upgrade from version 5 or version 6 to 9 is not supported.
Please visit this page for more information on the End-of-Life policy statement.