RESOLUTION
Choose any unused port and add it to the /etc/services file, for example:
smtp_alt 25025/tcp # new SMTP port
If you have 'xinetd' as super-server, make a copy of /etc/xinetd.d/smtp_psa to /etc/xinetd.d/smtp_psa_alt and correct service line within new file:
service smtp_alt
Restart xinetd `/etc/init.d/xinetd restart` and SMTP connections will be accepted on the both standard and 25025 ports. You may also need to reconfigure Horde IMP (webmail) settings so it use alternative SMTP port too. This can be done in /etc/psa-horde/imp/servers.php file under smtpport parameter for both IMAP and POP3 servers.
grep '^smtp ' /etc/inetd.conf | sed 's/^smtp/smtp_alt/' >> /etc/inetd.conf and restart inetd.
NOTE: If you wish to disable default (25) port completely and continue using alternate one only, please do not block 25 port at firewall and do not remove 'smtp_psa' service from xinetd/inetd but set default SMTP service be listened on 127.0.0.1 only by adding 'bind = 127.0.0.1' to /etc/xinetd.d/smtp_psa, otherwise SMTP service status will be displayed incorrectly in Plesk CP. Plesk determines SMTP service status by checking 25th port and the port number is hardcoded there.